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1.
This paper identifies a significant deficiency in the literature on the application of the Relative Gain Array (RGA) formalism in the case of singular matrices. Specifically, it is shown that the conventional use of the Moore–Penrose pseudoinverse is inappropriate because it fails to preserve critical properties that can be assumed in the nonsingular case. It is then shown that such properties can be rigorously preserved using an alternative generalized matrix inverse. 相似文献
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Effect of external electric field on the terahertz transmission characteristics of electrolyte solutions 下载免费PDF全文
Jia-Hui Wang 《中国物理 B》2021,30(11):110204-110204
We fabricated a microfluidic chip with simple structure and good sealing performance, and studied the influence of the electric field on THz absorption intensity of liquid samples treated at different times by using THz time domain spectroscopy system. The tested liquids were deionised water and CuSO4, CuCl2, NaHCO3, Na2CO3 and NaCl solutions. The transmission intensity of the THz wave increases as the standing time of the electrolyte solution in the electric field increases. The applied electric field alters the dipole moment of water molecules in the electrolyte solution, which affects the vibration and rotation of the whole water molecules, breaks the hydrogen bonds in the water, increases the number of single water molecules and leads to the enhancement of the THz transmission spectrum. 相似文献
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Oded Stark 《The Journal of mathematical sociology》2020,44(3):138-146
ABSTRACTCombining a standard measure of concern about low relative wealth and a standard measure of relative risk aversion leads to a novel explanation of variation in risk-taking behavior identified and documented by social psychologists and economists. We obtain two results: (1) Holding individual i’s wealth and his rank in the wealth distribution constant, the individual’s relative risk aversion decreases when he becomes more relatively deprived as a result of an increase in the average wealth of the individuals who are wealthier than he is. (2) If relative deprivation enters the individual’s utility function approximately linearly then, holding constant individual i’s wealth and the average wealth of the individuals who are wealthier than he is, the individual’s relative risk aversion decreases when he becomes more relatively deprived as a result of a decline in his rank. Our findings provide a theoretical support for evidence about the propensity of relatively deprived individuals to gamble and resort to other risky behaviors. 相似文献
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由于NH3在大气气溶胶化学中具有重要作用,所以快速和精确反演NH3浓度对环境问题非常重要.本文以9.05μm的室温连续量子级联激光器(quantum cascade laser,QCL)作为光源,采用波长扫描直接吸收可调谐二极管激光吸收光谱(tunable diode laser absorption spectroscopy,TDLAS)技术,研究了QCL在1103.4 cm–1的光谱特性,获得了激光器控制的温度电流与波长的关系.设计了QCL二级温控的低压实验平台,测量氨气在1103.4 cm–1处的6条混叠吸收线,在降低压强的情况下谱线展宽变小,使混叠光谱分离,由此计算各条吸收线的线强,进一步对测量不确定度进行分析.针对混叠严重的光谱提出了低压分离单光谱精确反演气体浓度的方法,并进行了实验验证.通过与HITRAN数据库进行结果对比,得出氨气在1103.4 cm–1的实验测量线强值与数据库偏差为2.71%-4.71%,实验测量线强值的不确定度在2.42%-8.92%,极低压条件下反演浓度与实际值的偏差在1%-3%. 相似文献
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We optimized photocatalytic hydrogen production over TiO2-based photocatalyst by varying the dopant (nickel and copper oxide), thin film active area, nature and concentration of sacrificial agents, and light intensity in a photoelectrochemical (PEC) cell/dye-sensitized solar cell (DSSC). Various characterization techniques have been used to investigate the structural, morphological, optical, and PEC behavior of single and codoped TiO2. The TiO2 decorated with both Cu and Ni oxides with active area of 1 cm2 in a mixture of 5 vol % glycerol and 1 M KOH under light intensity of 100 mWcm?2 produced the maximum hydrogen of 338.4 μmol cm?2 for 2 h. The superior photocatalyst performance of this photocatalyst is attributed to its small crystallite size and large pore size, as confirmed by X-ray diffractometer, Transmission electron microscopy (TEM), and surface area of Brunauer-Emmet-Teller (SBET). The absorption edges of this photocatalyst had the highest red shift compared with single doped and pure TiO2 because of more indirect transitions of the photoexcited electrons, greater charge carrier separation, and lower recombination rate. The photoanode active area of 1 cm2 with better photocatalytic performance correlated with the number of defects and grain boundaries. Glycerol shifted the conduction band of the photocatalyst to more negative flat potential compared with others. Increasing the concentration of glycerol further than 5 vol% saturated the photocatalyst active sites, increased photooxidation intermediates of glycerol, and reduced the hydrogen production. The light intensity had the maximum impact on the hydrogen production and could strongly control the number of charge carriers in both the PEC cell and the DSSC. 相似文献
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氟氧化物兼有氧化物优异的稳定性和氟化物的低声子能量,是上转换发光材料的一种热点基质材料,因而研究六方相LaOF∶Er,Yb的上转换发光性能及其温度特性具有重要意义。本文采用水热法制备了六方相LaOF∶Er,Yb荧光材料,通过X射线衍射(XRD)、扫描电镜(SEM)和荧光光谱对其结构和上转换荧光性能进行表征。实验结果表明,水热法120℃得到六方相LaF3,经800℃和1000℃退火后分别形成四方相LaOF和六方相LaOF。980 nm激发下,六方相LaOF∶Er,Yb中Yb3+与Er3+存在能量传递,通过双光子吸收产生绿光和红光的上转换荧光,并且Yb3+与Er3+的最佳浓度分别为3%和1%。最后研究了六方相LaOF∶Er,Yb在温度传感方面的应用,其在150~400 K温度范围的相对灵敏度和绝对灵敏度分别为0.037 K-1和0.0043 K-1。该材料具有优异的温度传感特性,对荧光温度传感器件的设计和应用具有指导意义。 相似文献